Flash Fire is an ability introduced in generation 3.
25 Pokémon can have this ability, such as Vulpix, Ninetales, Growlithe, Arcanine and Ponyta. For 6 of them it is the hidden ability, usually obtained from events, raids or breeding.
Official effect
Protects against Fire moves. Once one has been blocked, the Pokémon's own Fire moves inflict 1.5× damage until it leaves battle.